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C12000 C12200 Copper Plate

General Description C12200, Phosphorus deoxidised copper, has been made weldable and brazeable by deoxidising with phosphorus. It is widely used as flat products and tubing, especially where it is to be welded or brazed. Phosphorus significantly reduces the conductivity, which may go as low as 70% IACS, but also raises the softening temperature when work hardened and promotes fine grain size.

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Product Introduction

AS2738.2 – 1984, Compositions & Designations

Copper (including silver)

Phosphorus

> 99.90%

0.015 – 0.040%

Equivalent Alloy Specifications

Specification

Designation

UNS

C12200

BSI

C106

ISO

Cu-DHP

JIS

C1220

Australian Product Specifications

Specification

Product Form

AS1432

Copper Tubes for Water, Gas & Sanitation

AS1566

Rolled Flat Products

AS1567

Wrought Bars & Sections

AS1572

Seamless Tubes for Engineering Purposes

ASTM Product Specifications

Specification

Title

B5

High Conductivity Tough Pitch Copper Refinery Shapes

B42

Seamless Copper Pipe, Standard Sizes

B68

Seamless Copper Tube, Bright Annealed

B75

Seamless Copper Tube

B88

Seamless Copper Water Tube

B111

Copper and Copper Alloy Seamless Condenser Tubes and Ferrule Stock

B152

Copper Sheet, Strip, Plate and Rolled Bar

B187

Copper Bar, Bus Bar, Rod and Shapes

B280

Seamless Copper Tube for Air Conditioning and Refrigeration Field Service

B302

Threadless Copper Pipe

B306

Copper Drainage Tube (DWV)

B359

Copper and Copper Alloy Seamless Condenser and Heat Exchanger Tubes With Integral Fins

B360

Hard Drawn Copper Capillary Tube for Restrictor Applications

B379

Phosphorized Coppers – Refinery Shapes

B395

U Bend Seamless Copper and Copper Alloy Heat Exchanger and Condenser Tubes

B447

Welded Copper Tube

B543

Welded Copper and Copper Alloy Heat Exchanger Tube

B577

Detection of Cuprous Oxide (Hydrogen Embrittlement Susceptibility) in Copper

B640

Welded Copper and Copper Alloy Tube for Air Conditioning and Refrigeration Service

B698

Seamless Copper and Copper Alloy Plumbing Pipe and Tube

B743

Seamless Copper Tube in Coils

B837

Seamless Copper Tube for Natural Gas and Liquified Petroleum (LP) Gas Fuel Distribution Systems

Fabrication Properties

Joining Technique

Suitability

Soldering

Excellent

Brazing

Excellent

Oxy Acetylene Welding

Good

Gas Shielded Arc Welding

Good

Coated Metal Arc Welding

Not Recommended

Resistance Welding – Spot

Fair

Resistance Welding – Seam

Fair

Fabrication Technique

Suitability

Capacity for Being Cold Worked

Excellent

Capacity for Being Hot Worked

Good

Hot Working Temperature

750 – 950 °C

Annealing Temperature

250 – 650 °C

Stress Relieving Temperature

200 – 250 °C

Machinability Rating

20% of free cutting brass

Polishing/Electroplating Finish

Excellent

Mechanical Properties

AS1567, Wrought Rods, Bars & Sections

 

Temper

Thickness

Grain Size

Minimum Tensile Strength

Minimum Elongation

Maximum Hardness

Product

 

mm

mm

MPa

%

HV

Plate & Rolled Bar

Annealed, M or O

3.2 – 60.0

210

35

50*

 

Hard

3.2 – 12.0

280

15

85*

Sheet, Strip & Foil

Annealed, O4

 

0.025 – 0.045

220*

45*

60

 

1/2 Hard

0.15 – 3.2

245

10

75 – 90

 

Hard

0.15 – 3.2

310

7

90 – 115

Typical

Available Forms Shanghai Capway are able to supply this alloy as sheet, strip & tube.

General Description C12200, Phosphorus deoxidised copper, has been made weldable and brazeable  by deoxidising with phosphorus. It is widely used as flat products and tubing, especially where it is to be welded or brazed. Phosphorus significantly reduces the conductivity, which may go as low as 70% IACS, but also raises the softening temperature when work hardened and promotes fine grain size.

C12200 has almost exactly the same mechanical properties as the high purity copper alloys such as C11000. It has excellent deep drawing characteristics and resistance to pitting corrosion when exposed to severe weather and water environments.

Typical applications Tubes for hot & cold water, gas & heating installations, soil & waste pipes, storage tanks, cisterns & cylinders, rainwater goods, roofing, fascias, building facades, evaporators, heat exchangers, stills, vats, chemical equipment, anodes for electroplating baths.

Physical Properties

Property

Metric Units

Imperial Units

Melting Point (Liquidus)

1083°C

1981°F

Melting Point (Solidus)

1083°C

1981°F

Density

8.90 gm/cm³ @ 20°C

0.321 lb/in³ @ 68°F

Specific Gravity

8.90

8.90

Coefficient of Thermal Expansion

17.7 x 10 -6 / °C (20-300°C)

9.83 x 10 -6 / °F (68-392°F)

Themal Conductivity

293-364 W/m. °K @ 20°C

169-211 BTU/ft³/ft/hr/°F @ 68°F

Thermal Capacity (Specific Heat)

385 J/kg. °K @ 20°C

0.092 BTU/lb/°F @ 68°F

Electrical Conductivity

0.41-0.52 microhm?¹.cm?¹ @ 20°C

70-90% IACS @ 68°F

Electrical Resistivity

2.5-1.9 microhm.cm @ 20°C

15-12 ohms (circ mil/ft)@ 68°F

Modulus of Elasticity (tension)

115 GPa

17 x 10 6 psi

Modulus of Rigidity (torsion)

44 GPa

6.4 x 10 6 psi

Poisson’s Ratio

0.33

0.33

Corrosion Resistance

C12200 has similar corrosion resistance to C11000. It gives excellent resistance to weathering and very good resistance to many chemicals. It is often used specifically for corrosion resistance. It is suitable for use with most waters, and can be used underground because it resists soil corrosion. It resists non-oxidising mineral and organic acids, caustic solutions and saline solutions.

Depending on concentration and specific conditions of exposure, copper generally resists:

Acids: mineral acids such as hydrochloric and sulphuric acids; organic acids such as acetic acid (including acetates and vinegar), carbolic, citric, formic, oxalic, tartaric and fatty acids; acidic solutions containing sulphur, such as the sulphurous acid and sulphite solutions used in pulp mills.

Alkalies: fused sodium and potassium hydroxide; concentrated and dilute caustic solutions.

Salt solutions: aluminium chloride, aluminium sulphate, calcium chloride, copper sulphate, sodium carbonate, sodium nitrate, sodium sulphate, zinc sulphate.

Waters: all potable waters, many industrial and mine waters, seawater and brackish water.

Other media: The corrosion resistance of C12200 is not adequate for: ammonia, amines and ammonium salts; oxidizing acids such as chromic and nitric acids and their salts; ferric chloride; persulphates and perchlorates; mercury and mercury salts. Copper may also corrode in aerated non oxidising acids such as sulphuric and acetic acids, although it is practically immune from these acids if air is completely excluded. Copper is not suitable for use with acetylene, which can react to form an acetylide which is explosive.

Consult Shanghai Capway for your specific application.

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